DAMN!!! She still looks really pissed about having to lace those boots up! Maybe you should have a side zipper on them so she will smile once in a while. The only other thing that I can think of that would give her a scowl like that is a monster wedgie from the skintight bodysuit she is wearing, but she doesn't have an extra toe so it might not be that bad yet.
On a completely different note, I can identify the props she is using but can't place the boots or bodysuit, care to elaborate? Feel free to note me if you don't want to tell everyone.
The body suit is the same one I used from here :thumb296350118: - it's the ShadowCaster suit from Daz3d for V4 [link] The textures are from this set by ParrotDolphin at Renderosity [link] I did some tweaking to get the tiling the way I wanted.
You will be lucky if she doesn't choke you with those boot laces! I found it looking through my library, and remembered why I never use it, it doesn't have all the morphs I like to use. I liked the buckles at the neck was the reason I asked but I guess I will have to figure out how to use the Wardrobe Wizard in Poser to see if I can add what I want to it. Thanks for letting me know what you used for her uniform. Parrot Dolphin makes some amazing shaders, I was surprised you linked me to one I didn't have.